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Creators/Authors contains: "Xu, Vivian"

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  1. ; ; ; ; ; ; (, ASPET discovery)
    Free, publicly-accessible full text available February 27, 2027
  2. ; ; ; ; ; ; ; ; ; (, Drug Metabolism and Disposition)
    Free, publicly-accessible full text available September 1, 2026
  3. ; ; ; ; ; (, Drug Metabolism and Disposition)
    Free, publicly-accessible full text available May 1, 2026
  4. ; ; ; ; (, Dalton Transactions)
    This work centers around the nickel complexes derived from two tetrahydrosalen-type proligands: N , N ′-bis(2-hydroxybenzyl)- o -phenylenediamine (H 2 salophan) and N , N ′-bis(2-hydroxy-3-methylbenzyl)- o -phenylenediamine (H 2 salophan_Me). The reaction of H 2 salophan with Ni(OAc) 2 ·4H 2 O generates a dinuclear complex Ni 2 (Hsalophan) 2 (OAc) 2 or Na[Ni 2 (salophan) 2 (OAc)] when NaOH is added to assist ligand deprotonation. The reaction of H 2 salophan_Me with Ni(OAc) 2 ·4H 2 O, however, yields a mononuclear complex Ni(Hsalophan_Me) 2 . Unlike the corresponding salen-type nickel complexes, these tetrahydrosalen-type complexes are paramagentic and air sensitive (in solution). Oxidation by O 2 or peroxides results in dehydrogenation of the ligand backbone to form the salen-type complexes. 
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